EPJ E Highlight - How water can split into two liquids below zero
- Published on 17 January 2017
Theoretical possibility of the coexistence of dual liquid states of matter in sub-zero water due to the origami-like stacking behaviour of microscale moleculesy
Did you know that water can still remain liquid below zero degrees Celsius? It is called supercooled water and is present in refrigerators. At even smaller temperatures, supercooled water could exist as a cocktail of two distinct liquids. Unfortunately, the presence of ice often prevents us from observing this phenomenon. So physicists had the idea of replicating the tetrahedral shape of water molecules - using DNA as a scaffold to create tetrahedral molecules - and thus removing the interference of ice formation. This approach allowed Simone Ciarella from the University of Rome, Italy, and his colleagues to confirm that, in theory, a dual liquid phase is possible in sub-zero water and any other liquids made of tetrahedral molecules. These results have been published in EPJ E. It is a great tale of how the underlying microscopic shape determines the overall macroscopic form.
EPJ E Colloquium: Non-local fluctuation phenomena in liquids
- Published on 19 December 2016
Fluids in non-equilibrium steady states exhibit long-range fluctuations which extend over the entire system. They can be described by non-equilibrium thermodynamics and fluctuating hydrodynamics that assume local equilibrium for the thermophysical properties as a function of space and time.
The experimental evidence for the consistency between this assumption of local equilibrium in the equations and the non-local fluctuation phenomena observed is reviewed in this EPJ E colloquium paper
EPJ E Highlight - Physicists reveal cocktails with Dr Jekyll and Mr Hyde features
- Published on 02 November 2016
Study explains how long-range effects in two-liquid cocktails have a bearing on the diffusion of their molecules, resulting in the coexistence of different characteristics within the same fluid
Disturbing a mix of two liquids can yield some surprising effects. For example, if one portion of the mixture is brought to a different composition, it starts a process called diffusion, which continues until the liquid mix reverts to the resting point, which physicists refer to as equilibrium. Understanding the underlying physical phenomenon matters because diffusion is ubiquitous in physical and biological processes, such as the transport of nutrients within our cells. Now, an Italian team of physicists has found that two-liquid cocktails display long-range correlations, both at equilibrium and when disturbed. This means that large regions with slightly different physical properties coexist within the same fluid. Outside the equilibrium condition, the authors explain, this is due to the coupling between the difference in concentration between different portions of the liquid and spontaneous fluctuations, which are also observed when the mix is at equilibrium. These findings have been published in EPJ E as part of the Topical Issue "Non-isothermal transport in complex fluids" by Fabio Giavazzi from the University of Milan, Italy, and colleagues. They imply that the long-range effects, observed when the mixture is not at equilibrium, need to be taken into account as an additional contribution to the effects observed when the mixture is at equilibrium, so as to understand the diffusion mechanisms.
EPJ E Colloquium: Self-consistent field theory of multicomponent wormlike-copolymer melts
- Published on 03 October 2016
The self-consistent field theory (FCFT) is a convenient theoretical tool to describe the ordered structures of copolymer melts. It supports the current understanding of many polymeric systems. In a new EPJ E Colloquium Ying Jiang and colleagues showcase the versatility and power of the wormlike-chain formalism for calculating the microphase-separated crystallographic structures of multi-component wormlike polymers.
EPJ E Review - Watching crystals grow
- Published on 08 August 2016
Crystallization, a typical self-organization process during which a disordered state spontaneously transforms into an ordered one, a crystal, usually proceeds by nucleation and growth. In the initial stages of the transformation, a localized nucleus of the new phase forms due to a random fluctuation. Most of these small nuclei disappear after a short time, but in some rare cases a crystalline embryo may reach a critical size, after which further growth becomes thermodynamically favorable and the entire system is converted into the new phase.
In this EPJ E review paper, Jungblut and Dellago discuss several theoretical concepts and computational methods to better understand crystallization. More specifically, they address the rare event problem arising in the simulation of nucleation processes, and explain how to calculate nucleation rates accurately. Particular emphasis is placed on discussing statistical tools to analyze crystallization trajectories and identify the transition mechanism.
EPJ E Highlight - Asymmetrical magnetic microbeads transform into micro-robots
- Published on 19 July 2016
Thanks to the ordering effects of two-faced magnetic beads, they can be turned into useful tools controlled by a changing external magnetic field
Janus was a Roman god with two distinct faces. Thousands of years later, he inspired material scientists working on asymmetrical microscopic spheres - with both a magnetic and a non-magnetic half - called Janus particles. Instead of behaving like normal magnetic beads, with opposite poles attracting, Janus particle assemblies look as if poles of the same type attract each other. A new study reveals that the dynamics of such assemblies can be predicted by modelling the interaction of only two particles and simply taking into account their magnetic asymmetry. These findings were recently published in EPJ E by Gabi Steinbach from the Chemnitz University of Technology, Germany, and colleagues at the Helmholtz-Zentrum Dresden-Rossendorf. It is part of a topical issue entitled "Nonequilibrium Collective Dynamics in Condensed and Biological Matter." The observed effects were exploited in a lab-on-a-chip application in which microscopic systems perform tasks in response to a changing external magnetic field.
Regine von Klitzing wins the 2016 EPJE Pierre-Gilles de Gennes Lecture Prize
- Published on 12 July 2016
The EPJE editors are pleased to announce that this year’s edition of the EPJE Pierre-Gilles de Gennes Lecture Prize goes to German physicist Regine von Klitzing. Von Klitzing was nominated for her important contributions to polymer physics, particularly concerning the structure of polyelectrolyte assemblies and functionalized/responsive microgels. The EPJE Pierre-Gilles de Gennes lecture will be delivered by von Klitzing in Grenoble, France, during the 4th International Soft Matter Conference which takes place from 12 to 16 September 2016.
EPJ E interview – Daan Frenkel. Simulating soft matter through the lens of statistical mechanics
- Published on 23 June 2016
Daan Frenkel has been awarded the most important prize in the field of statistical mechanics, the 2016 Boltzmann Medal. The award recognises Frenkel’s seminal contributions to the statistical-mechanical understanding of the kinetics, self-assembly and phase behaviour of soft matter. The honour recognises Frenkel’s highly creative large-scale simulations of soft matter capable of explaining the self-assembly of complex macromolecular systems, colloidal and biomolecular systems.
Frenkel is Professor of Theoretical Chemistry at the University of Cambridge, UK and has been Editor in Chief of EPJ E between 2010 and 2014. In this interview with Sabine Louet, Frenkel gives his views on statistical physics, which has become more relevant than ever for interdisciplinary research. He also offers some pearls of wisdom for the next generation Statistical Mechanics experts. The full interview is published in the June issue of EPJE.
EPJ E interview – Yves Pomeau. The universality of statistical physics interpretation is ever more obvious
- Published on 23 June 2016
During the StatPhys Conference on 20th July 2016 in Lyon, France, Yves Pomeau and Daan Frenkel will be awarded the most important prize in the field of Statistical Mechanics: the 2016 Boltzmann Medal. The award recognizes Pomeau’s key contributions to the Statistical Physics of non-equilibrium phenomena in general. And, in particular, for developing our modern understanding of fluid mechanics, instabilities, pattern formation and chaos.
Pomeau, who is an Editor for the European Physical Journal Special Topics, is recognised as an outstanding theorist bridging disciplines from applied mathematics to statistical physics with a profound impact on the neighbouring fields of turbulence and mechanics. In an interview with Sabine Louet, published in EPJ E, Pomeau shares his views and tells how he experienced the rise of Statistical Mechanics in the past few decades. He also touches upon the need to provide funding to people who have the rare ability to discover new things and ideas, and not just those who are good at filling in grant application forms. The full interview is published in the June issue of EPJE.
EPJ E Highlight - Versatile method yields synthetic biology building blocks
- Published on 14 June 2016
New high-throughput method to produce both liposomes and polymersomes on the same microfluidic chip
Synthetic biology involves creating artificial replica that mimic the building blocks of living systems. It aims at recreating biological phenomena in the laboratory following a bottom-up approach. Today scientists routinely create micro-compartments, so called vesicles, such as liposomes and polymersomes. Their membranes can host biochemical processes and are made of self-assembled lipids or a particular type of polymers, called block copolymers, respectively. In a new study, researchers have developed a high-throughput method--based on an approach known as microfluidics--for creating stable vesicles of controlled size. The method is novel in that it works for both liposomes and polymersomes, without having to change the design of the microfluidic device or the combination of liquids. Julien Petit from the Max Planck Institute for Dynamics and Self-Organisation (MPIDS) in Göttingen, Germany and colleagues recently published these findings in EPJ E.